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	<journal>
		<journal_title>eEarth</journal_title>
		<journal_url>www.electronic-earth.net</journal_url>
		<issn>1815-381X</issn>
		<eissn>1815-3828</eissn>
		<volume_number>4</volume_number>
		<issue_number>1</issue_number>
		<publication_year>2009</publication_year>
	</journal>
	<doi>10.5194/ee-4-15-2009</doi>
	<article_url>http://www.electronic-earth.net/4/15/2009/</article_url>
	<abstract_html>http://www.electronic-earth.net/4/15/2009/ee-4-15-2009.html</abstract_html>
	<fulltext_pdf>http://www.electronic-earth.net/4/15/2009/ee-4-15-2009.pdf</fulltext_pdf>
	<start_page>15</start_page>
	<end_page>22</end_page>
	<publication_date>2009-07-08</publication_date>
	<article_title content_type="html">Morphology of the pore space in claystones – evidence from BIB/FIB ion beam sectioning and cryo-SEM observations</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>G. Desbois</name>
			<email>g.desbois@ged.rwth-aachen.de</email>
		</author>
		<author numeration="2" affiliations="1">
			<name>J. L. Urai</name>
		</author>
		<author numeration="3" affiliations="2">
			<name>P. A. Kukla</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Geologie &amp;ndash; Endogene Dynamik, RWTH Aachen University, Lochnerstr. 4&amp;ndash;20, 52056 Aachen, Germany</affiliation>
		<affiliation numeration="2" content_type="html">Geological Institute, RWTH Aachen University, Wüllnerstr. 2, 52062 Aachen, Germany</affiliation>
	</affiliations>
	<abstract content_type="html">The morphology of pore space has a strong effect on mechanical and transport
properties of mudrocks and clay-rich fault gouge, but its characterization
has been mostly indirect. We report on a study of Boom clay from a proposed
disposal site of radioactive waste (Mol site, Belgium) using high resolution
SEM at cryogenic temperature, with ion beam cross-sectioning to prepare
smooth, damage free surfaces. Pores commonly have crack-like tips, preferred
orientation parallel to bedding and power law size distribution. We define a
number of pore types depending on shape and location in the microstructure:
large jagged pores in strain shadows of clastic grains, high aspect ratio
pores between similarly oriented phyllosilicate grains and crescent-shaped
pores in saddle reefs of folded phyllosilicates. 3-D reconstruction by
serial cross-sectioning shows 3-D connectivity of the pore space. These
findings offer a new insight into the morphology of pores down to nano-scale
in comparison to traditional pore size distributions calculated from mercury
Injection experiments, explain slaking of clays by successive wetting and
drying and provide the basis for microstructure-based models of transport in
clays.</abstract>
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</article>

